In the present work, the complexed oxidation products of propane-1, 2-diol and crotonaldehyde with TBC and TAC in various molar ratio have been studied. Out of the elements present (C, H, O & Cr) carbon and hydrogen were estimated instrumentally whereas chromium was determined by volumetric analysis. The possible formulation for the different products (complexes) obtained were tried with the help of empirical formula and the infrared spectra of the complexed products. We have taken TBC and TAC as oxidants for simple organic compounds like diols and enals like propane-1, 2-diol and crotonaldehyde. The products formed were analysed on the basis of elemental analysis, estimation, spectroscopic and thermal studies.